You can download opensuse for free, I'm not never used suse before, but I think 10.2 is the latest, so 9 might be a little out dated, for both ease of use and security.
I would recommend updating first, it doesn't really matter which distribution you choose, but setting up a webserver is very simple and straight forward,
just google "setting up apache + linux (insert distro title here)"
same for mail server, provided that your ISP allows you to run one, (I know mine does not unless I upgrade).
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