If you use multiple desktops, then it's more than easy to forget that in one of them you have your filemanager open on the CD. Although, having said this, I have had instances where I could not eject my DVD. I was not in the current directory, I did not have any filemanagers open on the DVD. I was not running any programs accessing the DVD, and yet I was still getting 'device is busy' message. It would sort itself out after about 5 mins. Weird.
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