I am sure that it is possible in theory...
You need to know the following:
(a) The partition layout on the HDD in question and the type of file system that Win 2K is installed on.
(b) If the Boot/Recover CD has drivers for the USB hub (UHCI, OHCI, or EHCI) and filesystem in (a).
You need to create a temporary folder so that you can mount the
partition (that the OS is installed on) to it.
Also, create another temporary folder so you can mount the USB stick to it.
You need to 'dmesg' to find out if the correct modules are loaded for the USB stick, and to find the partition on the stick - usually only one and something like /dev/sdb1 - it depends on the USB slot and if anything else is plugged in to one of them.
Once this is done, then just mount the HDD partition, and the stick to their temp folders, then 'cd' into the correct folder on the HDD and 'cp' the file in question to the temp folder for the USB stick.
Hope this helps.
J.
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