Assuming you are using OpenOffice 3.x ...
Here's one possibility. Safer to rename the directory that remove it, though.
Alternatively you could simply move ~/.openoffice aside by renaming it. If that fixes the problem it would show that the problem is caused by something within ~/.openoffice.
Moving ~/.openoffice aside would loose all your personal customisation; if re-creating it would be a lot of work, you could browse ~/.openoffice trying to find the files (incl. ownerships and permissions) that are causing the problem. EDIT: maybe ~/.openoffice.org/3/user/registry/data/org/openoffice/Office/Recovery.xcu