Well the rpm command is
Code:
rpm -Uvh package.rpm
given that the package is in the directory where you run that command (otherwise provide full path to the rpm file). The uppercase U should upgrade the package (or install if it isn't installed, if I'm not mistaken). Yum is for installing packages from reposities, if you do it locally, use rpm instead. If you have several files, you can use wildcards to install them all. Or to install graphically, just double-click on the rpm file and you should be prompted for a password, after which the package is installed if possible.
Upgrading glibc isn't like upgrading Totem, it's more ground-level thing - not sure how rpm handles it, but if the procedure isn't straightforward, it should warn you
EDIT: oh and do get the correct version of that package first. There are a lot of operating systems/distributions that use rpm package management, and they are not necessarily "compatible" with each other - so even if the package did install, it doesn't mean it would work without problems, or at all, depending on how much the OS differs from your OS that the package was meant for. So when downloading rpm packages manually, make sure they are meant for CentOS - and the exact version you're using, if possible, to avoid problems. Different distribution version packages should install, but it's not guaranteed they work without problems.