I am not sure how PoP is configured but usually postfix only listens to localhost (internal only) by default. Some programs use postfix to send messages like cron so it is nothing to worry about.
As a check you can install nmap if not already and test port 25
Code:
nmap localhost -p 25
Starting Nmap 6.40 ( http://nmap.org ) at 2021-10-05 ...
Nmap scan report for localhost (127.0.0.1)
Host is up (0.000065s latency).
Other addresses for localhost (not scanned): 127.0.0.1
PORT STATE SERVICE
25/tcp open smtp
nmap IP_address -p 25
Starting Nmap 6.40 ( http://nmap.org ) at 2021-10-05...
Nmap scan report for server (IP_address)
Host is up (0.000060s latency).
rDNS record for 192.168.0.2: server
PORT STATE SERVICE
25/tcp closed smtp
Where IP_address is the private IP address of your computer. Look at the output of the command ip a. Your actual output might be different but the line that starts with inet is your LAN address.
Code:
2: enp0s25: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc pfifo_fast state UP group default qlen 1000
link/ether bc:30:5b:b9:d1:5a brd ff:ff:ff:ff:ff:ff
inet 192.168.0.2/24 brd 192.168.0.255 scope global noprefixroute dynamic enp0s25