Being off line doesn't make any difference on this computer, I wonder if your firefox is looking for something online, can't think what or why thou.
If you tick the "work off line" box, does firefox start in that mode next time?? If it does, that may help.
Another thought is to navigate to your web page with nautilus then try open with firefox, instead of starting firefox first.
Only random thoughts, may not help very much.
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