Trying to boot an existing drive is going to be trouble. The install that you already have is set up to boot with your actual hardware, whereas vmware emulates an entirely different virtual machine. The only advice I can give you is to boot your computer into w2k server, then remove ALL the drivers, then reboot into Slack and try booting vmware. Then you'll need to install new drivers that are compatible with the virtual machine. After this, you won't be able to boot the (actual, physical) machine into w2k.
Good Luck, and keep us posted.
Enjoy!
--- Cerbere
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