1) To unplug the device, make sure you are not in the /mnt/muvo directory on any virtual terminal, then type 'umount /mnt/muvo'. This unmounts the Muvo's filesystem, and you can then safely unplug it. In Windows, ejecting the device (as opposed to the 'safely disconnect' option) actually charges it via USB, and the same functionality can apparently be replicated by passing the eject command "eject /dev/sda" (I have a perfectly good AC adaptor so I don't need to, but it's worth keeping in mind)
2) For adding it to the fstab, this is my entry:
/dev/muvo /mnt/muvo vfat noauto,users,rw,sync,dirsync 0 0
(Replace /dev/muvo with /dev/sda on your system)
noauto: stops it mounting at bootup if it's plugged in
users: Any user can mount and umount the device (as opposed to 'user', where a user can only mount it)
rw: Mounts the volume as readable and writable
sync: Synchronises all I/O operations. If you don't set this, then any operations you do on the Muvo, won't be carried out until you unmount the drive, which really isn't very helpful (e.g. deleting folders and adding new ones, then discovering the next day it hasn't...)
dirsync: Similiar to above. Not sure if it's needed if sync is alredy set, but better safe than sorry.
To mount it, you would just need to type 'mount /mnt/muvo'. If it gives any errors due to the options, try removing them and adding them back one by one to figure out the offending one.
Reasons not to add? If you have different USB/SCSI devices plugged in at the same time, the Muvo may not always be /dev/sda. (With udev on the 2.6 kernels you can get round this problem, but that's another story for another time, should you ever take the plunge to upgrade the kernel). Asides from that, it should work fine.
3) It looks like Hotplug is being started by default, so you don't need to issue 'hotplug start'
4) Try
MuVOn for editing playlists on the Muvo2 in Linux (although I haven't tried it, as I tend to just choose an album directory on the Muvo2 and play everything in that.)