Modify the /etc/group file. Add the additional users as a comma seperated format after the last colon of the file. In the future you can specify which groups a user should belong to with the 'useradd' command and the -G option.
Code:
NAME
group - user group file
DESCRIPTION
/etc/group is an ASCII file which defines the groups to which users belong. There is one entry per line, and each line
has the format:
group_name:passwd:GID:user_list
The field descriptions are:
group_name
the name of the group.
password
the (encrypted) group password. If this field is empty, no password is needed.
GID the numerical group ID.
user_list
all the group memberâs user names, separated by commas.
---------- Post added 05-02-12 at 02:48 PM ----------
Also, the /etc/password file has the primary GID of the user assigned there. So if you want to change their primary group you will need to modify that to the numerical GID of the group. The first post will let you add supplementary groups to your user.