It says basically the same as google:
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Apr 11 23:46:59 hostname postfix/smtp[17965]: 5C3961D84B5: to=<user@domain.com>, relay=ASPMX.L.GOOGLE.com[209.85.223.16]:25, delay=3.3, delays=0.02/0.01/0.23/3, dsn=5.1.1, status=bounced (host ASPMX.L.GOOGLE.com[209.85.223.16] said: 550-5.1.1 The email account that you tried to reach does not exist. Please try 550-5.1.1 double-checking the recipient's email address for typos or 550-5.1.1 unnecessary spaces. Learn more at 550 5.1.1
http://mail.google.com/support/bin/a...py?answer=6596 15si15905946iwn.6 (in reply to RCPT TO command))
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The same reject occurred for another user and a few personal accounts I have.
I dabbled with the settings, and Postfix is now working. "relayhost = $mydomain" is no longer set in the latest settings. Could that be the cause? According to the guide, relayhost is supposed to be set. Here's the latest config output:
[root@hostname log]# postconf -n
alias_database = hash:/etc/aliases
alias_maps = hash:/etc/aliases
command_directory = /usr/sbin
config_directory = /etc/postfix
daemon_directory = /usr/libexec/postfix
debug_peer_level = 2
html_directory = no
inet_interfaces = loopback-only
mail_owner = postfix
mailq_path = /usr/bin/mailq.postfix
manpage_directory = /usr/share/man
mydestination = $myhostname, localhost.$mydomain, localhost
mydomain = example.com
myhostname = mail.example.com
myorigin = $mydomain
newaliases_path = /usr/bin/newaliases.postfix
queue_directory = /var/spool/postfix
readme_directory = /usr/share/doc/postfix-2.3.3/README_FILES
sample_directory = /usr/share/doc/postfix-2.3.3/samples
sendmail_path = /usr/sbin/sendmail.postfix
setgid_group = postdrop
unknown_local_recipient_reject_code = 550