I don't know what is the usage of /etc/sysconfig/i18n, because I guess it's distro specific and my distro (Slackware) does not have it. All I know is that i18n is the Internationalization Project. There is also a directory named i18n where the various locales and font settings for each locale are defined.
Also in /etc/profile you define a variable you want to set globally.
Regards
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