You should be able to use dd to create an .iso from the DVD, and then dd to write the .iso to the thumb drive. If the target machine can boot from USB it should work. Very crudely it will look like this:
Step 1
dd if=/your/optical/drive of=/some/location/windows7.iso
Step 1a:
Do @michaelk's guidance from Post #5 (below this one) on the iso
Step 2
dd BS=4M if=/some/location/windows7.iso of=/your/usb/drive conv=fdatasync
Use lsblk or some other means to figure out your optical drive and USB device's actual names (e.g. /dev/sr0 and /dev/sdc).
If you want to see this in 'guide' format:
Scroll down to the 'linux' section, in the second part (after the Brasero example):
https://www.howtogeek.com/228886/how...mac-and-linux/
Writing to the USB device is basically those directions 'in reverse' - you will select the created .iso as the if (Input File) and the USB device as the of (Output File). If you want to see more directions, they have the 'inverse' in another article (
https://www.howtogeek.com/414574/how...rive-in-linux/ - scroll down to the 'dd' section).