You didn't resize the filesystem. You run into the same problem if you enlarge a partition without adjusting the filesystem structure to make use of the space. Fortunately, enlarging the filesystem can still be done.
Code:
fsadm resize /dev/VolGrp0/home
Most filesystems will allow you to do that while mounted. You could have avoided the extra step by including the "--resizefs" option in your
vgextend command.
FYI, when going in the other direction (shrinking), it is
imperative that the filesystem either be shrunk first or as part of the
lvreduce or
lvresize operation. Omitting that leads to a corrupted filesystem, which might or might not be recoverable depending on what else you did before you realized your error.