you can either just stick the script into the end of the local service script, normally /etc/rc.local but if you did want to have it as a proper "service" after the mount is done, then take a simple service file in the /etc/init.d directory and modify where appropriate to make the start routine execute the script. once that works, create a symlink from that file to the /etc/rc?.d directorys, using a name of S??servicename where ss is the order / priority you wish.
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