ifconfig eth0 down
ifconfig eth0 hw ether 12:34:56:78:91:01
ifconfig eth0 up
You bind MAC's to hardware, not IP schemes.
The Media Access Control (MAC) sublayer is the part of the OSI network model data link layer that determines who is allowed to access the physical media at any one time. It acts as an interface between the Logical Link Control sublayer and the network's physical layer.
The MAC sublayer is primarily concerned with the control of access to the physical transmission medium (i.e. which of the stations attached to the wire or frequency range has the right to transmit?) or low-level media-sharing protocols like CSMA/CD.
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