Ok, assuming your motherboard is really a P5LD2-X/1333 and not the one you listed, on page X of the manual it says that it is only rated for:
Quote:
2 x 240-pin DIMM sockets support unbuffered non-ECC
Memory
DDR2 400/533/667 memory modules
Supports up to 2 GB system memory
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Which would indicate to me that this is another example of Intel using a 32bit memory controller on a 64bit motherboard. Which (memory wise) means that no matter what OS you are using(64bit or 32bit) your are going to be stuck with the 32bit limit.