I suggest you look around for other threads before asking this. (there are way too much threads about not being able to boot to Windows)
But besides that, if you have a bootfloppy/cd, then when you turn on the computer, go to the BIOS Setup (usually by hitting Del or F10, depending on what the screen says at startup), then go to the tab Boot, in there, you can find Boot Priority (or Priorities), there you can choose to give the floppy/cd-rom higher priority than the harddisc, after that, go back to the main menu and choose Exit & Save Changes, the computer will reboot, and if the bootfloppy/cd is in the drive, it will boot off that, instead of loading GRUB.
Hope this helps.
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