it is most likely becuase your windows drive is not getting mounted.
therefore it is probably a problem with your fstab.
if you have the proper entry in your fstab and you have automount installed, then your windows drive will be mounted at boot-time.
is your windows filesystem fat32 or ntfs?
do this as root:
mkdir /mnt/c
if you have a fat32 fs do this:
mount -t vfat /dev/hd?? /mnt/c
if it is ntfs do this:
mount -t ntfs /dev/hd?? /mnt/c
where ?? is the drive and partition of your drive
ie hda1, hdb1, etc...
look at man fstab to find out how to set up your fstab
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