Ok, I don't have any files to test this on. But this one liner is meant to be entered in a terminal at the prompt. It assumes that you are converting <filename>.wmv files in the current directory to <filename>.pcm files, again in the current directory. If that was your intention you could simply cut the following line and paste it at the command prompt.
Code:
for i in *wmv; do mencoder $i -ovc copy -oac pcm -o "${i}.pcm"; done
Let me know if this is what you're after?
Regards,
Fordeck