The easiest way is to create an empty file named "forcefsck" in the root directory. Just run "touch /forcefsck" as root. Then reboot, and all file systems will be checked except for those flagged as not to be checked in /etc/fstab ("0" in the 6th field).
If you don't want to check everything, an alternative is to boot into "emergency mode," in which the normal root partition is mounted read-only, and therefore checkable, and nothing else is mounted. Instructions for booting in emergency mode can be found at
https://access.redhat.com/knowledge/...emergency.html. (That's for RHEL 5, but RHEL 6 is the same in that regard.)