From the command line, if you enter
you will receive something similar to this:
32-bit
Linux computer_name 2.6.32-358.0.1.el6.i686
64-bit
Linux computer_name 2.6.32-358.0.1.el6.x86_64
Linux = OS
computer_name = name of the computer
2.6.32-358.0.1.el6 = kernel version
i686 = 32-bit designation
x86_64 = 64-bit designation