Did u restart the postfix service after making the changes. This is the only parameter by which attachment size limit can be set.
By default limit is 10MB. You can change the limit using
postconf command. To check the current limits you can run
postconf -d | grep message_size
It will show you the size in bytes.
To change the value
Run
postconf -e 'message_size_limit = 20000000'
postconf -e 'mailbox_size_limit = 100000000'
This will accept messages of sizes up to 20000000 bytes, and the max. mailbox size is then limited to 100000000 bytes. Use whatever values you like. Restart Postfix afterwards:
/etc/init.d/postfix restart
Regards
Ramesh Kumar
http://linuxtrove.com