Hye
Yes, they are all enterprise products. The documentation for all mentioned products is available for free.
So take a look at
Symantec tech support site and at
sun documentation website.
Both companies provide learning courses and certification paths, but they are all heavily expensive. I did classroom training for VxVM/VCS and Netbackup, this takes around 20k $ in Europe, but they were very helpful on my step to certification.