OptiFine_1.16.4_HD_U_G5 (1).jar is not the same as OptiFine.jar. There are several ways of dealing with this.
One is:
Code:
chmod +x /home/compudopt/Downloads/OptiFine{tab}
which means type the start of the filename and then press the Tab key, which will autocomplete the filename, or at least to the first variance if there are multiple files with similar names. Or you can be even less specific and use
Code:
chmod +x /home/compudopt/Downloads/OptiFine*
which will make every file in the directory which starts with OpiFine executable.