http://www.Knoppix.com/
http://www.linux-live.org/
LiveCD or LiveUSB.
Boot from a LiveCD.
This will help you get your feet wet with a known good Linux/GNU system.
Get the latest LiveCD (say from Knoppix), boot from CD and enjoy.
Again, using the Knoppix LiveCD as an example;
Boot from CD, Knoppix will scan hardware and setup for KDE GUI operation.
You now have a fully functional Linux Operating System with the KDE GUI.
You are running from a CD so you can always boot, no harddrive needed only memory.
Once booted you can mount harddrives and look at Windows partitions, rename files, change the administrator password, fix the registry, erase files infected with virus, start a web server, start a ftp server, surf the internet, write Word documents with OpenOffice.
Unless you change the harddrive, nothing is permanent.
For more control, try a LiveUSB boot and finally wipe Windows away and install a good Linux/GNU distribution (Fedora, Unbuntu, Gentoo).