As far as I remember, the PoPToP server (or you're using something else?) has an option which allows/disallows client-to-client communication. But I may confuse these parameters with ones of OpenVPN.
You may also use firewall, as all traffic will go through the server anyway. I'm sure this solution will do its job.
ps: I've checked the official
website of the poptop project and haven't find any appropriate options.
The only one which seemed to me more or less useful is
proxyarp, you can find the description:
http://poptop.sourceforge.net/dox/options.pptpd.txt
But I'm not sure (due to weakness of my English ;-) if it's what yu wish to have.