You have a routing problem at this point.
Quote:
a) one Windows XP (IP 192.168.0.1)
B) to another linux Box (IP 192.168.0.100)
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Standard network masks for these networks are 255.255.255.0.
That means that your first card gets all addresses from within 192.168.0.1 until 192.168.0.254.
If you can you should change one network to another address space.
For example:
a) one Windows XP (IP 192.168.0.1)
B) to another linux Box (IP 192.168.1.100)
If you want to use both network cards on the same subnet i am not sure how you could manage this cleanly.
But if there are just a few fixed addresses behind each card you can setup host routes. However that would need you to change the routes each time the network structure changes.
Chris