You can't get rid of application data by dropping network packets. The mail server will attempt to deliver mails according to the way it's configured, and by preventing it from contacting the recipient server, you've only ensured that the mails will stay in the queue until they are removed by some other action (manual deletion, automatic deletion with NDRs etc).
You need to reroute
mails, not network traffic. Since you're using Postfix, perhaps the method outlined in
these articles could be used.