Thanks Stony for the reply. After a little guidence and a couple of hours tinkering I found out that the problem was one of the NIC's. It just wouldn't come up. I swapped it out for another 3Com and away we went.
As it turns out you can just have > auto eth1 with no IP address and Ntop picks it up without any fuss. Seems the dns error I was getting from my web page we a missing dependency for Ntop. So a quick re-install got me back on track.
Now it off to do battle with and other Debian box and RRD Tool and Cacti. Yee Haw!
Thanks again for the post.
Cheers