You can usually leave that empty. It is only really needed with multiple graphics cards.
But if you'd like to fill in the value for it:
Execute
Code:
lspci | grep -i vga
That should produce output that looks something like this:
Code:
0000:03:00.0 VGA compatible controller: nVidia Corporation: Unknown device 00f1 (rev a2)
The numbers there in the beginning are the interesting ones. The first four zeros you can ignore, but the last three number units is the one you use.
In this case the PCI ID would be
PCI:3:0:0
More generally, if the numbers there are 0000:X:Y.Z, then the PCI ID you specify in the X configuration is PCI:X:Y:Z