The /etc/default/grub file has this line at the top: GRUB_DEFAULT=0
Modify it to what you want, count down the menuentry lines to the one you want as default. Count starts at zero (0).
Just because an entry is the first in the menu doesn't mean it is the default. Check the /etc/default/grub file against your grub.cfg.
Quote:
I still cannot reach XP Prof and it is on the grub menu .
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That's not much to go on. We can't see your grub.cfg file?