Hit a few snags, mostly to do with the host system. Gentoo x86_64 truly is not an ideal system to build off of. So I will just use the LiveCD.

EDIT: Well that was stupid of me. I decided to go with the slackware pkgtools for package management (instead of using symlinking), and used a chroot inside a chroot to install a particular app to make a pkg. So I binded /tools to /path/to/app/build/tools. When everything was done, I decided to issue rm -rf /path/to/app/build without unbinding the tools folder and ended up wiping out my toolchain. Now I need to rebuild it. I = fail.

*sigh*

UPDATE: Ran in to problems with building GCC (missing some header files for one reason or another), and lack of motivation to solve said problem, I decided to ditch this attempt. Will try again some day down the road.