In Deepin, "Default Applications" is the menu entry you need in Control Centre. However, in my version 15.3 there is no option to change the file manager. The other regular items are there though. I would try what frankbell has suggested by going to "open with" in the right click dialogue.
Sadly, as much as Deepin likes to innovate, and come up with their own in house alternatives, in the case of their file manager there is a long way to go yet with it. I notice in some instances I can't get rid of it as a default. I have installed both Thunar and Nautilus - both have their advantages for me.
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