I don't know which bootloader Ubuntu uses, but you need to edit the relevant config file: menu.lst for GRUB (found in /boot/grub usually) or lilo.conf (on Slackware at least, this is in /etc) for LILO.
For GRUB:
There's a line in the file that says "default x", where x is the number of the default entry. Counting begins from 0, so the first entry in the file would be 0, the second would be 1 and so on. Simply change the number to whatever corresponds to your Windows entry and save the file.
For LILO:
The relevant line in lilo.conf is "default=label", where "label" corresponds to whatever string the "label=" line of your Windows entry is set to. After making the change, save the file and run "/sbin/lilo".
HTH.
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