21 : Selected disk does not exist
This error is returned if the device part of a device- or full
file name refers to a disk or BIOS device that is not present or
not recognized by the BIOS in the system.
That's what the error means. Apparently the hardware detection hasn't progressed far enough for grub to find a bootable OS on the external USB drive, but after ctrl+alt+del, it has been detected.
You might want to check your BIOS to see if there is anything there to setup.
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