The default option of a column is that it can hold duplicate values. If you make the column a primary key or add a UNIQUE constraint, than it can't hold duplicates.
I'm guessing in your case it's the first (primary key columns can NEVER have duplicates).
Maybe you should give a detailed explanation of your problem (table layouts, primary keys, foreign key relationships). That way we can help you out, right now it's all kind of blury.
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