You should verify that the following (well, at least the port number) are correct for authenticated connections:
Code:
host 10.99.193.72
port 25
Typically SMTP servers that listen on port 25 do not employ user authentication. For example, Google uses port 465 (SSL) or 587 (TLS).
Take a look at this
page to get a better idea. These port settings may or may not apply to your current locale.