VCDs have dat files on them - as far as I know - is this a VCD you are trying to copy and play?
there are two ways I know of how to achieve what you are trying:
there is a tool called vcdimager (or similar) which will copy the whole VCD and not just the dat files
mplayer can play VCDs - and if it can play them it can also dump them to your disk.
to play it:
mplayer vcd://1
to dump it:
mplayer vcd://1 -dumpstream -dumpfile ...
this should work - I don't have VCDs but this worked with every format I ever had - I use it to dump DVDs to disk
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