As I udnerstand, you want to install XP on a slave disk, then install Linux on the master. I don't see any problem with that, it should work.
What I accidently discovered a few weeks back was the following:
I ran Mandrake 10 on my primary master and just had my backups on my secondary master which was fat32. I then disabled the Linux drive and installed windows on the secondary master. after that I enabled the Linux drive again. Take note that because the fat32 partition existed when I installed Linux, it already made a bootloader entry for windows. So after I re-enabled the Linux drive, I tried to boot to windows through LILO and it worked, so if you still have your second hard drive as a fat32 you can install Linux and use it until you need windows and only then install it the same way I did.
Hope this helps.
Regards,
Trickle
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