Some things to look at in the LibreOffice Help files:
1) Under 'table mode selection', look at the 'Fixed, proportional' settings for your table.
2) Under 'table cells', look at 'Changing Indents' for your table.
From your description, it sounds like the table is indented too far to the right. That is easily corrected with the indent triangles in the page horizontal ruler.
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