Along with the defaultRoot ~ (or the version of that for your FTP server) you can also make the user's home directories (which is the reason for the default ~) /var/www/html by editing /etc/passwd and changing that user's home directory. However, if you want everyone who ftp's into your box, whether it's anon or not, to have /var/www/html as their home directory, change:
DefaultRoot ~
to
DefaultRoot /var/www/html
You will have to give alot of permissions to that directory if you go that route(read/execute world, r,w,x group/owner).
Cool
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