It's definitely do-able. It is, of course, best to back up before this kind of adventure, and there is a chance of an unavoidable Windows reinstall, but probably that won't happen. There's two ways to try this. Install Mint on the spare drive, manually add the Windows boot to grub afterwards. Or, if you're particularly paranoid, remove the SSDs first, install Mint on the spare drive, then reinstall the SSDs and figure out grub afterwards. It is not unusual to have to manually fix grub.cfg, in my experience.
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