This has nothing to do with the Tk interface or ClamAV but with resolving host names. Running
Code:
dig +nocomments +noquestion +nostats +nocmd +noauth +noadditional -t A any database.clamav.net|grep CNAME
should show it resolve to "db.local.clamav.net" which in turn should resolve to "db.${YOUR_COUNTRY_CODE}.clamav.net". If your local resolver doesn't show that then check again but using your providers (or any publicly accessible name servers) instead.
*ClamAV may be security-related but your question isn't so I'll move it to the Linux Software forum.