Where to start? Let's try postfix.
Is it running? Post the output of the following commands to see if postfix is running and listening properly on TCP/25.
Code:
pgrep master
netstat -pantu
lsof -i4 -a
Let's check some of postfix's most relevant and foundational parameters. Post the output of the following command.
Code:
postconf myhostname mydomain myorigin mydestination mynetworks mynetworks_style relay_domains relayhost
Now let's send yourself a copy of /etc/fstab in a new email, and see what the logs show us. Please post the output of the tail command (log file entries by Postfix as it tries to deliver the email):
Code:
sendmail -f you@yourdomain.com you@yourdomain.com < /etc/fstab && tail -f /var/log/maillog
Should be pretty easy to figure out where the emails are going once you run the commands.