I am not sure I understand you correctly.
If you mean that the window of the program that is running on wine is too small, wine can't do anything about that. Some programs, and almost all the games, set a given screen resolution. Sometimes you can change it on the game setup, sometimes it's possible to do so by editing a given ini file or a key in the registry. It depends on the program.
Wine can't "zoom" windows magically if that's what you were asking.
However I think that compiz-fusion has a plugin to zoom windows, never tried it though.
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