there's no mynetworks definition, which is probably where your problem is coming from. mynetworks defines what sources can use you as a relay, ie. who can give it mail not destined for the server itself, but some other domain (i.e. who you are sending mail to at hotmail etc..) so add that and you'll see a big difference, e.g. mynetworks=192.168.1.0/24 for a fairly standard local subnet.
and mail isn't sent and recieved on port 25 the way you suggest. smtp servers pass mail to other smtp servers, which all listen on port 25. so if someone sends YOU mail, they connect to YOUR port 25. if you send someone else mail, you connect to THEIR port 25, so it's exactly the same process, but from the other side, yeah?
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