You can telnet on port 25 to the server in question and use the ehlo command, to see how it responds:
Code:
telnet server 25
250-servername ESMTP Sendmail 8.14.1/8.14.1 ...
250-ENHANCEDSTATUSCODES
250-PIPELINING
250-8BITMIME
250-SIZE
250-DSN
250-ETRN
250-AUTH DIGEST-MD5 CRAM-MD5
250-DELIVERBY
250 HELP
If it comes with 250-AUTH lines, it means that SMTP-AUTH works.
Regards