A lot more info is needed. What is the PCIe card? Is it graphics, sound, network, or what? Brand and model would be most useful. Exactly what did you copy into the /lib/firmware folder? As smallpond noted, it would be beneficial to post exact errors or logfiles concerning this. How does the system see the card? Open a terminal as root (not sudo) and type lspci and post the output that concerns the card in question.
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