If you are talking about applications (like LibreOffice, Firefox) rather than command-line tools, which HRH is talking about, then look in the control centre for the menu editor. If you right click on a program and choose the option "properties", there's a button to click on to set a shortcut for that application. You can use any special buttons you have on your keyboard, like "mail" or "media", or a combination using the Super key (the one with the Windows emblem). I use Super+c for a calculator, Super+t for the terminal, and so on: choose your own.
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